Department of Chemistry

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Jessica Anna

Professor

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Chevron Science Center
219 Parkman Avenue

Pittsburgh, PA 15260
412-648-8090

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Research Overview

Solar energy conversion, in both natural and artificial systems, involves the absorption of a photon that can then lead to a series of energy and electron transfer events. Research in the Anna group focuses on investigating these photoinduced processes in a variety of systems including natural photosynthetic complexes; isolated cofactors and artificial light harvesting chromophores; and bioinspired systems and photocatalyst. To investigate these systems we use pump-probe and multidimensional spectroscopies in the visible and mid-IR spectral regions. Through our studies, we aim to gain a deeper understanding of the fundamental processes and ultrafast dynamics that govern solar energy conversion, which could lead to further insight and chemical intuition into how to tune and optimize energy transfer pathways and electron transfer events in
artificial photosynthetic systems, organic photovoltaic materials,
and photocatalysts.

This research spans interests across the fields of natural
and artificial photosynthesis, photovoltaics, and photocatalysis.

The Anna Group is currently accepting new graduate students.

Awards

  • 2021 NSF CAREER Award
  • 2019 Alfred P. Sloan Research
  • 2016 DOE Early Career Award
  • 2014 Elliman Faculty Fellow at the University of Pennsylvania

Publications

“Observing Similarities and Differences in the Properties of Isostructural Niobium(V)/Tantalum(V) Coordination Compounds with Strong Pi-Donor Ligands,” M.H. Furigay, S. Chaudhuri, C. Li, J. Zhou, P. Pandey, R.F. Higgins, H. Gupta, P.J. Carroll, M.R. Gau, J.M. Anna*, G.C. Schatz*, E.J. Schelter* Inorg. Chem. 2023, 32, 19238-19247
“Resolving the Impact of Hydrogen Bonding on the Phylloquinone Cofactor through Two-Dimensional Infrared Spectroscopy,” P. G. Askelson, S. L. Meloni, A. M. Hoffnagle, J. M. Anna J. Phys. Chem. B 2022, 126 48, 10120 - 10135
“Probing Ligand Effects on the Ultrafast Dynamics of Copper Complexes via Midinfrared Pump–Probe and 2DIR Spectroscopies,” W. Weng, A. B. Weberg, R. Gera, N. C. Tomson, J. M. Anna J. Phys. Chem. B 2021, 125 44, 12228 - 12241
“Halogen Bonding Facilitates Intersystem Crossing in Iodo-BODIPY Chromophores,” D. M. Chenoweth, J. M. Anna J. Phys. Chem. Lett. 2020, 11 3, 877 - 884
“Ultrafast Solvation Dynamics and Vibrational Coherences of Halogenated Boron-Dipyrromethene Derivatives Revealed through Two-Dimensional Electronic Spectroscopy,” Y. Lee, S. Das, R. M. Malamakal, S. Meloni, D. M. Chenoweth, J. M. Anna J. Am. Chem. Soc. 2017, 139 41, 14733 - 14742